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A Novel Organometallic Aqua Complex of Technetium for the Labeling of Biomolecules: Synthesis of [<sup>99m</sup>Tc(OH<sub>2</sub>)<sub>3</sub>(CO)<sub>3</sub>]<sup>+</sup> from [<sup>99m</sup>TcO<sub>4</sub>]<sup>-</sup> in Aqueous Solution and Its Reaction with a Bifunctional Ligand
663
Zitationen
6
Autoren
1998
Jahr
Abstract
We present herein the first synthesis of the water and air stable organometallic aqua complex [<sup>99m</sup>Tc(OH<sub>2</sub>)<sub>3</sub>(CO)<sub>3</sub>]<sup>+</sup> directly from [<sup>99m</sup>TcO<sub>4</sub>]<sup>-</sup> in saline under 1 atm of CO. Subsequent substitution of the labile water ligands by a bifunctional ligand attachable to biomolecules enables the introduction of carbonyl complexes in life sciences in general and in nuclear medicine in particular. [...]
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